Lesson 3.2.5.4
3.2.5.4 Formation of coloured ions Quiz: AQA Chemistry, Unit 2
20 questions
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Lesson 3.2.5.4, Formation of coloured ions: 20 multiple choice questions for the AQA Chemistry (7405), Unit 2: Inorganic chemistry, written with Revision Ninja.
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The 20 questions
-
Transition metal complexes appear coloured because they absorb specific wavelengths of what?
- Visible light
- Infrared radiation
- Ultraviolet light
- Microwave radiation
-
When visible light is absorbed by a complex ion, d electrons move to what state?
- Ionised state
- Ground state
- Gaseous state
- Excited state
-
Which equation gives the energy difference between the ground and excited d electron states?
- delta E = nRT
- delta E = kT
- delta E = mc^2
- delta E = h x nu = hc/lambda
-
Which of these factors does NOT alter the d-orbital energy gap Delta E in a complex?
- Solution concentration
- Oxidation state
- Co-ordination number
- Ligand type
-
What is the wavelength of light absorbed when delta E = 3.98 x 10^-19 J? (h = 6.63 x 10^-34 J s, c = 3.00 x 10^8 m s-1)
- 600 nm
- 700 nm
- 500 nm
- 400 nm
-
A solution absorbs mainly red light. What colour does it appear?
- Yellow
- Red
- Blue-green
- Black
-
Which transition metal ion forms a characteristic pale green aqueous solution?
- Iron(III)
- Chromium(III)
- Iron(II)
- Copper(II)
-
What colour is observed when a complex ion absorbs light in the blue region?
- Green
- Yellow
- Blue
- Red
-
Replacing water ligands with ammonia ligands changes a complex colour by altering what?
- Ionisation energy
- Enthalpy change
- Activation energy
- Energy gap Delta E
-
Why do [Cu(H2O)6]2+ and [CuCl4]2- absorb different wavelengths of visible light?
- Different pH values
- Different Delta E
- Different solution temperatures
- Different copper isotopes
-
A solution has an absorbance reading that is directly proportional to concentration. Which law is being obeyed?
- Charles's law
- Hess's law
- Boyle's law
- Beer-Lambert law
-
Why is the aqueous zinc ion, Zn2+, colourless?
- Empty d subshell
- No d electrons
- Incomplete d subshell
- Full d subshell
-
What is the energy gap delta E for absorption of light with wavelength 600 nm? (h = 6.63 x 10^-34 J s, c = 3.00 x 10^8 m s-1)
- 9.9 x 10^-19 J
- 3.3 x 10^-19 J
- 6.6 x 10^-19 J
- 1.1 x 10^-19 J
-
Changing a complex ion's co-ordination number alters its colour by changing what?
- Speed of light
- Planck constant
- Energy gap Delta E
- Avogadro constant
-
Which d-block metal ion is colourless in aqueous solution due to a full d sub-shell?
- Manganese(II)
- Scandium(III)
- Titanium(III)
- Vanadium(IV)
-
Why does changing the ligand in a transition metal complex alter its colour?
- Changes oxidation state
- Alters d-orbital splitting
- Alters nuclear charge
- Changes atomic radius
-
Which transition metal ion gives a blue colour in aqueous solution?
- Na+
- Zn2+
- Ca2+
- Cu2+
-
Where do d electrons move when visible light is absorbed by a transition metal complex?
- Ground state
- Surrounding ligands
- Inner shells
- Excited state
-
What process causes light absorption in transition metal complexes?
- Thermal expansion
- Nuclear excitation
- d-electron promotion
- Ligand dissociation
-
What is the approximate wavelength in nm for light of energy 2.0 x 10^-19 J? (h = 6.63 x 10^-34 J s, c = 3.00 x 10^8 m s-1)
- 1000 nm
- 100 nm
- 3000 nm
- 500 nm
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