Lesson 3.3.15
3.3.15 Nuclear magnetic resonance spectroscopy Quiz: AQA Chemistry, Unit 3
20 questions
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Lesson 3.3.15, Nuclear magnetic resonance spectroscopy: 20 multiple choice questions for the AQA Chemistry (7405), Unit 3: Organic chemistry, written with Revision Ninja.
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The 20 questions
-
What information is directly determined from the chemical shift values in NMR spectra?
- Relative molecular mass
- Bond dissociation energy
- Environment of atoms
- Empirical formula
-
Why is tetramethylsilane used as a standard reference signal in NMR spectroscopy?
- Multi-peak splitting
- High boiling point
- Unreactive single peak
- Coloured solution
-
What unit is used to measure chemical shift on an NMR spectrum?
- Parts per million
- Grams per mole
- Hertz per metre
- Joules per mole
-
What does the integrated area under a peak in proton NMR spectroscopy show?
- Coupling constant
- Relative hydrogen count
- Carbon chain length
- Bond enthalpy
-
Why is carbon-carbon spin-spin splitting rarely observed in carbon-13 NMR spectra?
- High electronegativity
- Large atomic radius
- Zero nuclear spin
- Low natural abundance
-
Why is CDCl3 used as a solvent in proton NMR spectroscopy instead of CHCl3?
- Low density
- Strong acidity
- High boiling point
- No proton signal
-
How many peaks are seen in the 1H NMR spectrum of propanone?
- 6
- 2
- 3
- 1
-
How many environments of 1H are there in ethanol, CH3CH2OH?
- 3
- 4
- 1
- 2
-
What is the integration ratio of the three 1H environments in ethanol, CH3CH2OH?
- 1 : 2 : 3
- 2 : 3 : 1
- 1 : 1 : 1
- 3 : 2 : 1
-
Using the n+1 rule, what is the multiplicity of a CH3 group adjacent to a CH2 group?
- Singlet
- Doublet
- Triplet
- Quartet
-
What is the multiplicity of a CH2 group adjacent to a CH3 group?
- Quartet
- Triplet
- Singlet
- Doublet
-
In ethyl ethanoate, what is the multiplicity of the CH3 group attached to the C=O?
- Singlet
- Doublet
- Quartet
- Triplet
-
How many hydrogen atoms in total does ethyl ethanoate, CH3COOCH2CH3, contain?
- 6
- 4
- 10
- 8
-
A single peak integrating for nine protons in proton NMR indicates which structural group?
- Isopropyl group
- Phenyl group
- Ethyl group
- Tert-butyl group
-
How many 13C signals are expected from butanone, CH3CH2COCH3?
- 4
- 5
- 2
- 3
-
What is the chemical shift position of TMS in NMR?
- 200 ppm
- 100 ppm
- 10 ppm
- 0 ppm
-
Which compound's 1H NMR spectrum shows only a triplet (3H) and a quartet (2H)?
- Ethanoic acid, CH3COOH
- Ethanal, CH3CHO
- Bromoethane, CH3CH2Br
- Ethanol, CH3CH2OH
-
What effect causes different chemical shifts for nuclei in different environments in NMR?
- Molecular mass
- Electron shielding
- Nuclear spin
- Spin coupling
-
Why do protons near electronegative atoms shift downfield in 1H NMR spectroscopy?
- Spin-spin coupling
- Shielding
- Deshielding
- Hydrogen bonding
-
Which analytical technique identifies different carbon and hydrogen environments in organic compounds?
- Infrared spectroscopy
- Gas chromatography
- Mass spectrometry
- NMR spectroscopy
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