Lesson 3.3.8
3.3.8 Aldehydes and ketones Quiz: AQA Chemistry, Unit 3
20 questions
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Lesson 3.3.8, Aldehydes and ketones: 20 multiple choice questions for the AQA Chemistry (7405), Unit 3: Organic chemistry, written with Revision Ninja.
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The 20 questions
-
Which type of reaction is the reduction of an aldehyde by NaBH4?
- Free-radical substitution
- Elimination
- Nucleophilic addition
- Electrophilic substitution
-
What is the product when a ketone is reduced by NaBH4 in aqueous solution?
- An ester
- A carboxylic acid
- A secondary alcohol
- A primary alcohol
-
What toxic gas is released when potassium cyanide solution is acidified?
- Sulfur dioxide
- Hydrogen cyanide
- Ammonia gas
- Chlorine gas
-
Why does nucleophilic addition to an unsymmetrical aldehyde form a racemic mixture?
- Chiral reactant
- Free carbon rotation
- Planar carbonyl group
- Tetrahedral carbonyl carbon
-
Which reagent distinguishes aldehydes from ketones by forming a silver mirror?
- Tollens' reagent
- Fehling's solution
- Bromine water
- Acidified potassium dichromate
-
Which equation correctly shows the reduction of ethanal using [H] as the reductant?
- CH3CHO + 2[H] -> CH3COOH
- CH3CHO + [H] -> CH3CH2OH
- CH3CHO + 2[H] -> CH3CH2OH
- CH3CHO + [H] -> CH3COOH
-
What is the product when propanal reacts with HCN and then forms the hydroxynitrile?
- 2-hydroxypropanenitrile
- 2-hydroxybutanenitrile
- Propan-2-ol
- Butanoic acid
-
Why is the product of propanone reacting with KCN optically inactive?
- Insoluble in water
- Racemic mixture formed
- No chiral centre
- Contains double bonds
-
What is the role of dilute acid in the reaction of KCN with carbonyls?
- Protonate alkoxide ion
- Deprotonate carbonyl carbon
- Provide nucleophile
- Oxidise intermediate
-
What converts the alkoxide intermediate to an alcohol during reduction with aqueous NaBH4?
- Oxidation by oxygen
- Deprotonation by hydroxide
- Hydride ion attack
- Protonation by water
-
What organic product is formed when butanone is reduced by NaBH4?
- Achiral butan-2-ol
- Chiral butan-2-ol
- Achiral butan-1-ol
- Chiral butan-1-ol
-
What is the equation for the reduction of propanone by [H]?
- CH3COCH3 + [H] -> CH3CH2CH2OH
- CH3COCH3 + 2[H] -> CH3CH2COOH
- CH3COCH3 + 2[H] -> CH3CH(OH)CH3
- CH3COCH3 + [H] -> CH3COOH
-
Why can aldehydes be oxidised by Fehling's solution while ketones cannot?
- Hydroxyl O-H bond
- Carbonyl C-H bond
- Carbonyl C=O bond
- Carbonyl C-C bond
-
What organic product forms when ethanal is reduced by aqueous NaBH4?
- Ethene
- Ethanol
- Ethanal
- Ethanoic acid
-
Which ketone does NOT form a pair of enantiomers after reaction with KCN and dilute acid?
- Propanone
- Ethanal
- Pentan-2-one
- Butanal
-
What is the functional group formed when an aldehyde is oxidised?
- Alkene (C=C)
- Primary amine (-NH2)
- Ester (-COO-)
- Carboxylic acid (-COOH)
-
Which species acts as the nucleophile in the reaction of KCN with a carbonyl compound?
- Cyanide ion
- Water molecule
- Hydrogen ion
- Potassium ion
-
Which compound with formula C4H8O gives a silver mirror with Tollens' reagent?
- Butanone
- But-3-en-1-ol
- Cyclobutanol
- Butanal
-
What type of alcohol is formed when a ketone is reduced by NaBH4?
- Tertiary alcohol
- Primary alcohol
- Quaternary alcohol
- Secondary alcohol
-
What is the relative molecular mass of the hydroxynitrile formed from ethanal and HCN, CH3CH(OH)CN?
- 57
- 71
- 69
- 85
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