Lesson 13A.1
13A.1 Lattice energy and Born-Haber cycles Quiz: Pearson Edexcel Chemistry, Unit 13
20 questions
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Lesson 13A.1, Lattice energy and Born-Haber cycles: 20 multiple choice questions for the Pearson Edexcel Chemistry (9CH0), Unit 13: Energetics II, written with Revision Ninja.
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The 20 questions
-
Which enthalpy change forms one mole of an ionic solid from gaseous ions?
- Enthalpy of atomisation
- Lattice energy
- Ionisation energy
- Electron affinity
-
What is the sign of the lattice formation energy for ionic compounds?
- Variable
- Positive
- Negative
- Zero
-
Which enthalpy change forms one mole of gaseous atoms from an element?
- Lattice energy
- Enthalpy of atomisation
- Ionisation energy
- Enthalpy of formation
-
What process occurs during the first electron affinity of an atom?
- Losing one electron
- Gaining two electrons
- Sharing electrons
- Gaining one electron
-
Which enthalpy change forms one mole of a compound from its elements?
- Lattice energy
- Enthalpy of atomisation
- Enthalpy of formation
- Enthalpy of combustion
-
What does a more exothermic lattice energy indicate about an ionic compound?
- Stronger ionic bonding
- Lower melting point
- Higher solubility
- Weaker ionic bonding
-
Which law allows an unknown enthalpy change to be calculated using a Born-Haber cycle?
- Hess's law
- Henry's law
- Avogadro's law
- Raoult's law
-
Using dHf(NaCl) = -411, atomisation of Na = +107, first ionisation energy of Na = +496, half the bond energy of Cl2 = +121 and electron affinity of Cl = -349 (all in kJ mol-1), what is the lattice energy of NaCl?
- +786 kJ mol-1
- -786 kJ mol-1
- -375 kJ mol-1
- -411 kJ mol-1
-
Which ionic properties give magnesium oxide a much more exothermic lattice energy than sodium chloride?
- Higher charges, smaller radii
- Higher charges, larger radii
- Lower charges, larger radii
- Equal charges, larger radii
-
A Born-Haber cycle for an ionic compound has dHf = -600, atomisation of metal = +150, ionisation energy = +700, half bond energy = +100 and electron affinity = -50 (all kJ mol-1). What is the lattice energy?
- -300 kJ mol-1
- -900 kJ mol-1
- -1500 kJ mol-1
- +1500 kJ mol-1
-
What factor makes oxide formation energetically favourable overall in magnesium oxide?
- Large lattice energy
- Low ionisation energy
- Weak covalent bonds
- Zero electron affinity
-
How many chlorine electron affinity terms appear in the Born-Haber cycle for magnesium chloride?
- Two terms
- One term
- Three terms
- Four terms
-
Which of these ionic compounds has the largest magnitude of lattice energy?
- LiF
- NaCl
- MgO
- KBr
-
Which combination of ionic properties results in a more exothermic lattice energy?
- Higher charge, larger radius
- Lower charge, larger radius
- Lower charge, smaller radius
- Higher charge, smaller radius
-
A Born-Haber cycle for CaO has dHf = -635, atomisation of Ca = +178, IE1 + IE2 of Ca = +1735, atomisation of O = +249, EA1 of O = -141 and EA2 of O = +798 (kJ mol-1). What is the lattice energy of CaO?
- +3454 kJ mol-1
- -2184 kJ mol-1
- -635 kJ mol-1
- -3454 kJ mol-1
-
What does an experimental lattice energy that is more exothermic than the theoretical value indicate?
- Metallic bonding
- Delocalised bonding
- Pure ionic bonding
- Covalent character
-
Using dHf(KCl) = -437, atomisation of K = +89, IE of K = +419, half bond energy of Cl2 = +121 and lattice energy of KCl = -701 (kJ mol-1), what is the electron affinity of chlorine?
- +365 kJ mol-1
- -1046 kJ mol-1
- -365 kJ mol-1
- -701 kJ mol-1
-
For MgCl2, dHf = -641, atomisation of Mg = +148, IE1 + IE2 of Mg = +2189, bond energy of Cl2 = +242 (for two atoms, 2 x 121), and 2 x electron affinity of Cl = -698 (all kJ mol-1). What is the lattice energy?
- -2522 kJ mol-1
- +2522 kJ mol-1
- -1881 kJ mol-1
- -641 kJ mol-1
-
Which lithium halide has the most exothermic lattice energy?
- Lithium bromide
- Lithium chloride
- Lithium iodide
- Lithium fluoride
-
Besides lattice energy, which enthalpy change directly determines the enthalpy of solution for an ionic compound?
- Enthalpy of combustion
- Enthalpy of hydration
- Enthalpy of atomisation
- Ionisation energy
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