Lesson 15A.2

15A.2 Ligands, complex ions and coordination number Quiz: Pearson Edexcel Chemistry, Unit 15

20 questions

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Lesson 15A.2, Ligands, complex ions and coordination number: 20 multiple choice questions for the Pearson Edexcel Chemistry (9CH0), Unit 15: Transition Metals, written with Revision Ninja.

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The 20 questions

  1. What is the definition of a ligand in complex ions?

    • Electron-pair acceptor
    • Lone-pair donor
    • Proton acceptor
    • Proton donor
  2. What type of bond forms between a ligand and a central metal ion?

    • Metallic bond
    • Ionic bond
    • Dative covalent bond
    • Non-polar covalent bond
  3. What term describes a central metal ion surrounded by coordinately bonded ligands?

    • Free radical
    • Complex ion
    • Heterogeneous catalyst
    • Chelate effect
  4. What does the coordination number of a complex ion represent?

    • Overall ion charge
    • Total ligand count
    • Oxidation state value
    • Total dative bonds
  5. How many dative bonds does a monodentate ligand form with a metal ion?

    • Four
    • Two
    • Six
    • One
  6. Which compound acts as a bidentate ligand in transition metal complexes?

    • Ammonia
    • Chloride ion
    • Ethane-1,2-diamine
    • Water
  7. What is the shape of a complex ion with a coordination number of six?

    • Linear
    • Tetrahedral
    • Octahedral
    • Square planar
  8. What is the coordination number of the cobalt ion in [CoCl4]2-?

    • 6
    • 8
    • 4
    • 2
  9. What is the coordination number of the copper ion in [Cu(NH3)4(H2O)2]2+?

    • 2
    • 6
    • 8
    • 4
  10. What shape is usually formed by a complex ion containing four chloride ligands?

    • Octahedral
    • Tetrahedral
    • Linear
    • Square planar
  11. What is the oxidation state of cobalt in [CoCl4]2-?

    • +2
    • +6
    • +4
    • -2
  12. Which metal ion is present at the centre of a haemoglobin molecule?

    • Iron(II)
    • Cobalt(II)
    • Iron(III)
    • Copper(II)
  13. What is the shape of the anticancer drug cisplatin?

    • Octahedral
    • Tetrahedral
    • Square planar
    • Trigonal bipyramidal
  14. What thermodynamic factor makes multidentate ligands form more stable complexes?

    • Negative enthalpy change
    • Positive entropy change
    • Positive enthalpy change
    • Negative entropy change
  15. What colour change occurs when excess chloride ions are added to aqueous cobalt(II) ions?

    • Pink to blue
    • Yellow to green
    • Blue to pink
    • Green to pink
  16. Which species is a multidentate ligand with six donor atoms?

    • Cl-
    • H2O
    • EDTA4-
    • NH2CH2CH2NH2
  17. Which term describes the increased stability of complexes containing multidentate ligands?

    • Resonance effect
    • Template effect
    • Inductive effect
    • Chelate effect
  18. Why does replacing water ligands with chloride ligands reduce the coordination number?

    • Chloride is smaller
    • Chloride is larger
    • Chloride is neutral
    • Water is charged
  19. What effect do ligands have on the d orbitals of a central transition metal ion?

    • Split their energies
    • Remove all electrons
    • Fill them completely
    • Increase their degeneracy
  20. Which ligand in haemoglobin is replaced by carbon monoxide during poisoning?

    • Oxygen
    • Carbon dioxide
    • Nitrogen
    • Water

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