Lesson 3.3.6.2

3.3.6.2 Mass spectrometry Quiz: AQA Chemistry, Unit 3

20 questions

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Lesson 3.3.6.2, Mass spectrometry: 20 multiple choice questions for the AQA Chemistry (7405), Unit 3: Organic chemistry, written with Revision Ninja.

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The 20 questions

  1. What does the molecular ion peak in a mass spectrum indicate?

    • Bond vibration frequency
    • Empirical formula
    • Number of fragments
    • Relative molecular mass
  2. What process forms a molecular ion in electron impact mass spectrometry?

    • Gain of a proton
    • Homolytic fission
    • Loss of an electron
    • Heterolytic fission
  3. What can be determined using precise atomic masses in high-resolution mass spectrometry?

    • Empirical formula
    • Optical purity
    • Molecular formula
    • Functional groups
  4. Which molecular formula has a precise molecular mass of 44.0261?

    • N2O
    • CO2
    • C3H8
    • C2H4O
  5. A compound has a precise molecular ion mass of 58.0417. Which molecular formula fits?

    • C3H6O
    • C2H6N2
    • C4H10
    • C2H2O2
  6. A compound has a precise molecular ion mass of 60.0573. Which molecular formula fits?

    • C4H12
    • C2H4O2
    • C3H8O
    • CH4N2O
  7. Compound X has a precise molecular ion mass of 88.0522. Which molecular formula is correct?

    • C4H8O2
    • C3H8N2O
    • C3H4O3
    • C5H12O
  8. A compound has a precise molecular ion mass of 46.0417. Which molecular formula fits?

    • CH4NO
    • C2H6O
    • CH2O2
    • C3H10
  9. A compound has a precise molecular ion mass of 74.0729. Which molecular formula fits?

    • C3H10N2
    • C4H10O
    • C2H6N2O
    • C3H6O2
  10. A compound has a precise molecular ion mass of 102.0678. Which molecular formula fits?

    • C5H10O2
    • C4H10N2O
    • C6H14O
    • C4H6O3
  11. What type of mass spectrometry distinguishes between compounds with the same nominal mass?

    • Infrared spectroscopy
    • Chromatography
    • High resolution
    • Low resolution
  12. What process causes a molecular ion peak to be weak or absent in a mass spectrum?

    • Fragmentation
    • Polymerisation
    • Protonation
    • Ionisation
  13. A compound contains only carbon, hydrogen and nitrogen, and its precise molecular ion mass is 58.0530. Which formula fits?

    • C3H6O
    • C2H2O2
    • C4H10
    • C2H6N2
  14. What is the degree of unsaturation for C4H8O2?

    • 0
    • 2
    • 1
    • 3
  15. Which technique distinguishes between molecules with the same nominal mass of 44?

    • Flame photometry
    • High-resolution mass spectrometry
    • Low-resolution mass spectrometry
    • Thin-layer chromatography
  16. What value from high-resolution mass spectrometry is used to find an exact molecular formula?

    • Peak intensity
    • Retention time
    • Wavenumber
    • Precise molecular mass
  17. A compound has precise molecular ion mass 74.0366. Which molecular formula fits?

    • C3H6O2
    • C3H10N2
    • C2H6N2O
    • C4H10O
  18. What can be determined directly using precise atomic masses from high-resolution mass spectrometry?

    • Relative abundance
    • Molecular formula
    • Bond lengths
    • Empirical formula
  19. What is the degree of unsaturation for a molecule with formula C5H10O2?

    • 1
    • 0
    • 2
    • 3
  20. High-resolution mass spectrometry is primarily used to determine which molecular property?

    • Molecular formula
    • Bond angle
    • Molecular shape
    • Empirical formula

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