Lesson 18C.2

18C.2 Planning multi-step reaction schemes Quiz: Pearson Edexcel Chemistry, Unit 18

20 questions

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Lesson 18C.2, Planning multi-step reaction schemes: 20 multiple choice questions for the Pearson Edexcel Chemistry (9CH0), Unit 18: Organic Chemistry III, written with Revision Ninja.

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The 20 questions

  1. Which reagent dehydrates an alcohol to form an alkene?

    • Acidified potassium dichromate
    • Dilute sodium hydroxide
    • Aqueous potassium cyanide
    • Concentrated sulfuric acid
  2. What is the product of heating bromoethane with sodium cyanide in ethanol?

    • Ethanamide
    • Ethanenitrile
    • Butanenitrile
    • Propanenitrile
  3. Ethyl bromide reacts with magnesium in dry ether, then carbon dioxide, then dilute acid. What is the final organic product?

    • Propanoic acid
    • Butanoic acid
    • Ethanoic acid
    • Propan-1-ol
  4. A Grignard reagent reacts with ethanal, followed by aqueous acid. What type of alcohol is formed?

    • A tertiary alcohol
    • A secondary alcohol
    • A primary alcohol
    • A carboxylic acid
  5. A Grignard reagent reacts with propanone, followed by aqueous acid. What type of alcohol is formed?

    • A secondary alcohol
    • A primary alcohol
    • A tertiary alcohol
    • An alkene
  6. What type of alcohol is formed when a Grignard reagent reacts with methanal?

    • A primary alcohol
    • A tertiary alcohol
    • A carboxylic acid
    • A secondary alcohol
  7. Why must Grignard reagents be prepared in anhydrous conditions?

    • Evaporates too quickly
    • Requires light activation
    • Reacts with water
    • Reacts with nitrogen
  8. What is the first step in converting ethene into ethanoic acid?

    • Oxidation to ethanal
    • Reduction to ethane
    • Halogenation to bromoethane
    • Hydration to ethanol
  9. Which reagent increases the carbon chain length of 1-bromopropane?

    • Sodium borohydride
    • Potassium cyanide
    • Potassium dichromate
    • Potassium hydroxide
  10. Which reagent acetylates 2-hydroxybenzoic acid to produce aspirin?

    • Concentrated sulfuric acid
    • Ethanoic anhydride
    • Sodium borohydride
    • Ethanoic acid
  11. What is the main purpose of heating a reaction mixture under reflux?

    • Lowers activation energy
    • Prevents side reactions
    • Prevents reactant loss
    • Increases reaction rate
  12. A synthesis gives 3.5 g of product from a theoretical yield of 6.0 g. What is the percentage yield?

    • 43%
    • 86%
    • 58.3%
    • 70%
  13. Three steps each have a yield of 80%. What is the overall percentage yield?

    • 240%
    • 51.2%
    • 24%
    • 80%
  14. Why must ethanoyl chloride be used inside a fume cupboard?

    • Absorbs atmospheric oxygen
    • Releases toxic HCl
    • Explodes on contact
    • Releases chlorine gas
  15. Which reagent reacts with propanone to form 2-methylpropan-2-ol after acid work-up?

    • Acidified potassium dichromate
    • Sodium borohydride
    • Concentrated sulfuric acid
    • Methylmagnesium bromide
  16. Why is steam distillation used for water-insoluble, heat-sensitive organic compounds?

    • Prevents thermal decomposition
    • Increases boiling point
    • Increases reaction yield
    • Prevents oxidation reactions
  17. Which of these reaction types forms a new carbon-carbon bond?

    • Alcohol oxidation
    • Electrophilic addition
    • Grignard reaction
    • Free radical substitution
  18. Which piece of apparatus is fitted vertically to a flask during reflux?

    • Separating funnel
    • Buchner funnel
    • Fractionating column
    • Liebig condenser
  19. Calculate the overall percentage yield of a route with two steps giving 75% and 60% yields.

    • 135%
    • 67.5%
    • 15%
    • 45%
  20. What organic product forms when ethanol is heated under reflux with excess acidified potassium dichromate(VI)?

    • Ethene
    • Ethane
    • Ethanoic acid
    • Ethanal

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