Lesson 14.1.1
14.1.1 Standard electrode potentials and the hydrogen electrode Quiz: Pearson Edexcel Chemistry, Unit 14
20 questions
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Lesson 14.1.1, Standard electrode potentials and the hydrogen electrode: 20 multiple choice questions for the Pearson Edexcel Chemistry (9CH0), Unit 14: Redox II, written with Revision Ninja.
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The 20 questions
-
What is the assigned standard electrode potential of the standard hydrogen electrode?
- +1.00 V
- +0.10 V
- -1.00 V
- 0.00 V
-
Why must standard electrode potentials be measured relative to a reference electrode?
- Voltage changes rapidly
- Hydrogen is reactive
- Current flow varies
- Absolute values impossible
-
What standard pressure is used when measuring standard electrode potentials?
- 1 kPa
- 100 kPa
- 101 kPa
- 100 atm
-
Against which reference electrode are standard electrode potentials measured?
- Standard zinc electrode
- Standard hydrogen electrode
- Standard calomel electrode
- Standard copper electrode
-
What does a more negative standard electrode potential indicate about a species?
- Less easily oxidised
- Stronger oxidising agent
- Stronger reducing agent
- Weaker reducing agent
-
Which metal is the strongest reducing agent: Mg (E° = -2.37 V), Zn (-0.76 V), or Cu (+0.34 V)?
- Zinc
- Magnesium
- Hydrogen
- Copper
-
What is the standard electrode potential of the standard hydrogen electrode?
- -0.76 V, the Zn2+/Zn value
- 0.00 V, by definition
- +1.00 V, a concentration reference
- +0.34 V, the Cu2+/Cu value
-
What is the standard cell emf for a Zn/Zn2+ half-cell (E-zero -0.76 V) connected to a Cu2+/Cu half-cell (E-zero +0.34 V), with Cu2+ reduced?
- +0.42 V
- +1.10 V
- +0.76 V
- -1.10 V
-
What is E°cell for chlorine oxidising Fe²⁺ to Fe³⁺ (E° Cl₂/Cl⁻ = +1.36 V, Fe³⁺/Fe²⁺ = +0.77 V)?
- +0.59 V
- +2.13 V
- -0.59 V
- -2.13 V
-
Which standard cell diagram represents a cell formed from Zn²⁺/Zn and Cu²⁺/Cu electrodes?
- Zn(s)|Zn²⁺(aq)||Cu²⁺(aq)|Cu(s)
- Cu²⁺(aq)|Cu(s)||Zn(s)|Zn²⁺(aq)
- Cu(s)|Cu²⁺(aq)||Zn²⁺(aq)|Zn(s)
- Zn²⁺(aq)|Zn(s)||Cu(s)|Cu²⁺(aq)
-
Using E-zero Mg2+/Mg = -2.37 V and Ag+/Ag = +0.80 V, what is the standard emf of Mg + 2Ag+ gives Mg2+ + 2Ag?
- -1.57 V
- +3.17 V
- -3.17 V
- +1.57 V
-
Why might a reaction with a positive E°cell value fail to occur at a measurable rate?
- High activation energy
- Endothermic reaction
- Low reactant concentration
- Negative cell potential
-
How does increasing the concentration of Zn2+ ions affect the electrode potential of a Zn2+/Zn half-cell?
- More positive
- No effect
- Zero potential
- More negative
-
Which metal can displace iron from an aqueous Fe2+ solution given E°(Fe2+/Fe) = -0.44 V?
- Lead
- Copper
- Silver
- Zinc
-
What is the standard emf of a Zn/Zn2+ half-cell (E-zero -0.76 V) connected to Ag+/Ag (E-zero +0.80 V)?
- +1.56 V
- +0.04 V
- +0.76 V
- -1.56 V
-
What role does platinum play in the standard hydrogen electrode?
- Inert electrode conductor
- Decreases pH value
- Acts as oxidant
- Reacts with hydrogen
-
What is E°cell for Sn | Sn2+ || Pb2+ | Pb given E°(Sn2+/Sn) = -0.14 V and E°(Pb2+/Pb) = -0.13 V?
- -0.27 V
- -0.01 V
- +0.27 V
- +0.01 V
-
What is the standard aqueous ion concentration required for measuring standard electrode potentials?
- 0.50 mol dm-3
- 0.10 mol dm-3
- 2.00 mol dm-3
- 1.00 mol dm-3
-
By convention, how are standard electrode potential half-equations always written?
- Redox reactions
- Neutralisation equations
- Oxidation half-equations
- Reduction half-equations
-
What is the standard emf for Mg (anode, E-zero -2.37 V) and Zn2+/Zn (cathode, -0.76 V) with the magnesium oxidised?
- +1.61 V
- +3.13 V
- -1.61 V
- +0.61 V
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